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Document Details
Document Type
:
Article In Journal
Document Title
:
SYNTHESIS AND SPECTROSCOPIC STUDIES OF MOLYBDENUM (0) AND RUTHENIUM(II) COMPLEXES OF 2,2-DIPYRIDYLA
SYNTHESIS AND SPECTROSCOPIC STUDIES OF MOLYBDENUM (0) AND RUTHENIUM(II) COMPLEXES OF 2,2-DIPYRIDYLA
Document Language
:
Arabic
Abstract
:
The reaction between neutral electron donor ligand 2,2-dipyridylamine (dpa) with Mo(CO)6 or [Ru Cl2(CO)2]n in (1:1) molar ratio in refluxing THF affords Mo(CO)4 dpa and Ru Cl2(CO)2 dpa complexes in high yields. On the basis of spectroscopic studies it is suggested that the ligand (dpa) in these complexes acts as bidentate and coordinates to the metals through pyridine-N atoms rather than with the amino group. The complex Mo(CO)4 dpa reacts with iodine to give seven coordinated Mo(CO)3 dpaI2 complexes. All the complexes were characterised by their H-1-NMR, IR and elemental analyses.
Journal Name
:
JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN
Volume
:
15
Issue Number
:
1
Publishing Year
:
1993 AH
Added Date
:
Saturday, June 14, 2008
Researchers
Researcher Name (Arabic)
Researcher Name (English)
Researcher Type
Dr Grade
Email
أحمد عمر بغلف
Researcher
الكثيري م
Researcher
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