Document Details
|
Document Type |
: |
Article In Journal |
|
Document Title |
: |
2-Hy-droxy-2,3,5,10,11,11a-hexa-hydro-1H-pyrrolo-[2,1-c][1,4] benzodiazepine-5,11-dione 2-Hy-droxy-2,3,5,10,11,11a-hexa-hydro-1H-pyrrolo-[2,1-c][1,4] benzodiazepine-5,11-dione |
|
Subject |
: |
Chemistry |
|
Document Language |
: |
English |
|
Abstract |
: |
The seven-membered ring of the title compound, C12H 12N2O3, which is fused with the phenyl-ene ring, adopts a boat-shaped conformation (with the methine C atom as the prow and the phenyl-ene C atoms as the stern); the H atom on the methine linkage exists in an axial position. The five-membered ring that is fused with the seven-membered ring adopts an envelope conformation (with the C atom bearing the hy-droxy substituent representing the flap) [the deviation from the plane defined by the other four atoms is 0.200 (7) Å in one molecule and 0.627 (5) Å in the other]. The two independent molecules are disposed about a pseudo center of inversion and are connected by a pair of N - H⋯O hydrogen bonds. Adjacent dimers are linked by a pair of O - H⋯O hydrogen bonds, generating a chain running along the b axis. |
|
ISSN |
: |
1600-5368 |
|
Journal Name |
: |
Acta Crystallographica Section E: Structure Reports Online |
|
Volume |
: |
67 |
|
Issue Number |
: |
8 |
|
Publishing Year |
: |
1432 AH
2011 AD |
|
Article Type |
: |
Article |
|
Added Date |
: |
Saturday, December 10, 2011 |
|
Researchers
| S Ourahou | Ourahou, S | Researcher | Doctorate | |
| H Zouihri | Zouihri, H | Researcher | Doctorate | |
| M Massoui | Massoui, M | Researcher | Doctorate | |
| E M Essassi | Essassi, E M | Researcher | Doctorate | |
| Seik Weng Ng | Ng, Seik Weng | Researcher | Doctorate | seikweng@um.edu.my |
|
Back To Researches Page
|