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Document Details
Document Type
:
Article In Journal
Document Title
:
New Polymer Syntheses Part 57: Thermally Stable New Ferrocene-Polyazomethines, Synthetic Methodology, and Characterization
New Polymer Syntheses Part 57: Thermally Stable New Ferrocene-Polyazomethines, Synthetic Methodology, and Characterization
Document Language
:
English
Abstract
:
A new interesting category of higher thermally stable polyazomethines containing ferrocene in the polymers main chain 6a-e was synthesized by solution-polycondensation reaction of 1-(m-formylphenyl)-1'-(5-formyl-2-methoxyphenyl)-ferrocene monomer 4 with different aliphatic and aromatic diamines. A model compound 5 was synthesized from dialdehyde monomer 4 with aniline and was characterized by elemental and spectral analyses. The desirable resulting polymers were characterized by elemental and spectral analyses, in addition to solubility measurement using different solvents. The thermal properties of these polymers were evaluated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) measurements. The redox behaviours were studied for the ferrocene polymers in comparison with both the parent ferrocene monomer and the model compound by using cyclic voltammetry (CV).
ISSN
:
2090-9063
Journal Name
:
JOURNAL OF CHEMISTRY
Volume
:
2013
Issue Number
:
2013
Publishing Year
:
1434 AH
2013 AD
Article Type
:
Article
Added Date
:
Sunday, July 23, 2017
Researchers
Researcher Name (Arabic)
Researcher Name (English)
Researcher Type
Dr Grade
Email
M Abdel-Rahman
Abdel-Rahman, M
Researcher
M Hussein
Hussein, M
Researcher
K Aly
Aly, K
Researcher
A Sarhan
Sarhan, A
Researcher
Files
File Name
Type
Description
42169.pdf
pdf
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