Document Type |
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Article In Journal |
Document Title |
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Synthesis and environmental applications of cellulose/ZrO2 nanohybrid as a selective adsorbent for nickel ion Synthesis and environmental applications of cellulose/ZrO2 nanohybrid as a selective adsorbent for nickel ion |
Document Language |
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English |
Abstract |
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Cellulos/ZrO2 nanohybrid has been synthesized by simple growth of ZrO2 on cellulose matrix and characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), Fourier transforms infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). Interestingly, FESEM showed nanoparticles with an average size of 50 nm. The analytical potential of the newly prepared nanohybrid was studied for a selective extraction of nickel prior to its determination by inductively coupled plasma-optical emission spectrometry. The selectivity of nanohybrid was investigated toward eight metal ions, including Cd2+, Co2+, Cr3+, Cu2+, Fe3+, Ni2+, Zn2+ and Zr4+. Data obtained from the selectivity study showed that nanohybrid was the most selective toward Ni2+. The uptake capacity for Ni2+ was experimentally calculated and found to be 79 mg g(-1). Moreover, adsorption isotherm data of Ni2+ on nanohybrid was well fit with the Langmuir adsorption isotherm, strongly supporting that the adsorption process was mainly monolayer on homogeneous adsorbent surfaces. Finally, data of Ni2+ adsorption on nanohybrid as a function of contact time displayed that equilibrium kinetics are very fast |
ISSN |
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1359-8368 |
Journal Name |
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COMPOSITES PART B-ENGINEERING |
Volume |
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50 |
Issue Number |
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50 |
Publishing Year |
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1434 AH
2013 AD |
Article Type |
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Article |
Added Date |
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Monday, July 24, 2017 |
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Researchers
S Khan | Khan, S | Researcher | | |
K Amary | Amary, K | Researcher | | |
H Marwani | Marwani, H | Researcher | | |
A Asiri | Asiri, A | Researcher | | |
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